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Iridium-Catalyzed Enantioselective and Diastereoselective Allylation of Dioxindoles: A One-Step Synthesis of 3-AllyI-3-hydroxyoxindoles 期刊论文

编号：

4cba4c20-6020-4f38-9e5f-2a90478cb1ba
作者：

He, Rui#^[1]Wu, Shanchao^[1];Tang, Haoming^[1];Huo, Xiaohong^[1];Sun, Zhenliang*^[2]Zhang, Wanbin*^[1]
语种：

英文
期刊：

ORGANIC LETTERS ISSN：1523-7060 2018 年 20 卷 19 期 (6183 - 6187) ; OCT 5
收录：
摘要：

An iridium-catalyzed asymmetric allylation of dioxindoles, 3-hydroxyoxindoles, regulated by prosthetic groups has been accomplished under mild conditions. The methodology is applicable to a diverse array of 3-hydroxyoxindole and cinnamyl acetate substrates. A range of 3-ally'-3-hydroxyoxindoles containing vicinal tetrasubstituted and trisubstituted stereocenters can be efficiently synthesized in one-step with excellent enantioselectivity (up to >99% enaniomeric excess (ee)) and good diastereoselectivity (up to 11:1 diastereomeric ratio (dr)).
推荐引用方式
GB/T 7714：

He Rui,Wu Shanchao,Tang Haoming, et al. Iridium-Catalyzed Enantioselective and Diastereoselective Allylation of Dioxindoles: A One-Step Synthesis of 3-AllyI-3-hydroxyoxindoles [J].ORGANIC LETTERS,2018,20(19):6183-6187.
APA：

He Rui,Wu Shanchao,Tang Haoming,Huo Xiaohong,&Zhang Wanbin.(2018).Iridium-Catalyzed Enantioselective and Diastereoselective Allylation of Dioxindoles: A One-Step Synthesis of 3-AllyI-3-hydroxyoxindoles .ORGANIC LETTERS,20(19):6183-6187.
MLA：

He Rui, et al. "Iridium-Catalyzed Enantioselective and Diastereoselective Allylation of Dioxindoles: A One-Step Synthesis of 3-AllyI-3-hydroxyoxindoles" .ORGANIC LETTERS 20,19(2018):6183-6187.
入库时间：

10/23/2019 1:39:05 PM
更新时间：

10/23/2019 1:39:05 PM
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